Beilstein J. Org. Chem.2015,11, 1596–1613, doi:10.3762/bjoc.11.175
nanostructured fibers and rods by controlling the supramolecular assembly, oxidation states, and counter anions employed.
Keywords: conductingfibers; star-shaped molecules; supramolecular assembly; tetrathiafulvalene oligomers; Introduction
Tetrathiafulvalene (TTF) chemistry first attracted enthusiastic
solution are also available for preparing conducting nanofibers.
The fastener effect [57], which enhances the face-to-face interaction between the two TTFs, can be used to construct conducting nanostructured fibers in the neutral state, and doping of the fibers with iodine affords black conductingfibers
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Graphical Abstract
Figure 1:
Radially expanded TTF oligomers 1 and 2a,b.